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Record W1685050726 · doi:10.1002/mame.201400251

Reversibly Dispersible/Collectable Metal‐Organic Frameworks Prepared by Grafting Thermally Responsive and Switchable Polymers

2014· article· en· W1685050726 on OpenAlex
Heyang Liu, He Zhu, Shiping Zhu

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMacromolecular Materials and Engineering · 2014
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsMcMaster University
Fundersnot available
KeywordsMaterials scienceLower critical solution temperatureMethacrylateCopolymerAtom-transfer radical-polymerizationPolymerEthylene glycolPolymer chemistryGraftingChemical engineeringPolymerizationDispersion (optics)Composite material

Abstract

fetched live from OpenAlex

A reversibly dispersible/collectable metal‐organic framework (MOF) system has been developed. The MOF particles were modified by grafting the thermally switchable copolymers of 2‐(2‐methoxyethoxy)ethyl methacrylate and oligo(ethylene glycol) methacrylate through a surface‐initiated atom transfer radical polymerization (SI‐ATRP) approach. The resulted MOF materials preserved their original framework structure and could be readily dispersed in water at room temperature to form stable dispersions. The dispersed MOF particles could also be re‐collected by heating the dispersions to above the lower critical solution temperature (LCST) of the grafted copolymer. The dispersion and collection processes were reversible.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.180
Teacher spread0.177 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it