Critical Micelle Concentration of Micelles with Different Geometries in Diblock Copolymer/Homopolymer Blends
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Bibliographic record
Abstract
Abstract It is well‐known that A‐B diblock copolymers in selective solvents or A‐homopolymers can form micelles of different shapes. The critical micelle concentration (CMC) of three basic micelle shapes (lamellar, cylindrical, and spherical) are calculated using the self‐consistent field theory formulated in the grand canonical ensemble. For a given set of molecular parameters, the stable micelle morphology is determined by a comparison of the CMC. The results confirm that micelles undergo a sequence of shape transitions, lamellar → cylindrical → spherical, when the A‐block of the diblock copolymer becomes longer. The results also reveal details about the micelle structure, such as the core radius and corona thickness. This information can be used to understand the effect of homopolymer molecular weight and monomer–monomer interaction on the micelle morphologies. magnified image
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it