Enhanced Film Blowing of Polylactide by Incorporating Branched Chains and Stereocomplex Crystals
Bibliographic record
Abstract
Abstract Chain architecture is an influential parameter in melt processing of polymeric material. In this study effect of different chain structures on polylactide (PLA) film blowing process and on the final film properties was investigated. Blends of linear PLA with three branched poly(L-lactide)s with 4-arms star shaped, comb like and hyper branched structures were prepared by twin screw extruder. In another series of blending, poly(D-lactide) of these branched structures were used to obtain stereocomplex crystal. Operating window of blends were determined in a series of film blowing process experiments with different blow up and take up ratio and results were compared to linear PLA as a reference. Moreover, different characterization techniques were applied to determine the properties of produced films. It was found that addition of branched architecture and presence of stereocomplex in a linear PLA matrix result in a greater operating window for film blowing and improve mechanical and crystallization properties of blown films.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".