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Record W1824716710 · doi:10.1139/cjc-2015-0099

Revealing the parameters to design the habit modifiers for rock-salt crystals: empirical to rational approach

2015· article· en· W1824716710 on OpenAlexvenueno aff
Anik Sen, Sunirmal Barik, Ajeet Singh, Bishwajit Ganguly

Bibliographic record

VenueCanadian Journal of Chemistry · 2015
Typearticle
Languageen
FieldMaterials Science
TopicCrystallization and Solubility Studies
Canadian institutionsnot available
Fundersnot available
KeywordsChemistryImpuritySalt (chemistry)Crystal habitPartition coefficientSodiumHabitRational designSolventMineralogyChemical engineeringInorganic chemistryOrganic chemistryCrystallizationNanotechnologyMaterials science

Abstract

fetched live from OpenAlex

Morphology of rock-salt crystals can be influenced by internal and external factors like temperature, super saturations, solvent, and impurities. Many impurities and additives have been reported to date for the habit modification of common salt; however, the selection of such impurities is largely empirical. The partition coefficient or log P, which is a measure of hydrophobic hydrophilic property of a material, very aptly signifies the ability of additives to modulate the morphology of sodium chloride crystals. Application of the partition coefficient of additives led to the discovery of two new habit modifiers (cytosine and DMSO) for rock-salt crystals. The predicted results have been verified by experimental studies. Furthermore, the known habit modifiers and also the nonhabit modifiers for sodium chloride crystals corroborate the importance of this parameter to define the morphology of salt crystals. This study is of fundamental importance, which otherwise was rather empirical for the last two centuries.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.506
Threshold uncertainty score0.260

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.134
GPT teacher head0.309
Teacher spread0.175 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2015
Admission routes1
Has abstractyes

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