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Extraction, Liquid‐Liquid

2007· other· en· W1825610237 on OpenAlexaff
Geoffrey W. Stevens, Teh C. Lo, M. H. I. Baird

Bibliographic record

VenueKirk-Othmer Encyclopedia of Chemical Technology · 2007
Typeother
Languageen
FieldEngineering
TopicProcess Optimization and Integration
Canadian institutionsMcMaster University
Fundersnot available
KeywordsCoalescence (physics)Countercurrent exchangeSolventExtraction (chemistry)Supercritical fluid extractionContinuous phase modulationChromatographyLiquid–liquid extractionSolvent extractionPetrochemicalSettlingAqueous two-phase systemDispersion (optics)Aqueous solutionPartition coefficientChemistryMaterials scienceEngineeringThermodynamicsOrganic chemistryEnvironmental engineeringPhysics

Abstract

fetched live from OpenAlex

Abstract Liquid–liquid extraction, also known as solvent extracting, is a well‐established separation technique that depends on the unequal distribution of a solute between two immiscible liquids. The initial feed liquid containing the solute is brought into contact with a solvent that is selected to have a greater affinity for the solute. The partition of the solute can be enhanced by adding a chemical extractant to the solvent; this practice is widespread in the hydrometallurgical and nuclear industries. Most industrial extractors operate continuously with countercurrent flow of the two phases. In mixer–settlers, the phases are contacted as a well‐agitated dispersion of drops, which are then sent to settling tanks for phase disengagement. In extraction columns, the dispersed drops move countercurrently against the flow of the second (continuous) phase. The physics, chemistry, and practice of extraction, with brief descriptions of important industrial extraction processes and equipment, are presented. Research on hydrodynamic aspects of process design, eg, axial mixing, drop dispersion, and coalescence, is reviewed. New extraction techniques, eg, membrane extraction, supercritical exctraction, and two‐phase aqueous extraction, are discussed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.027
Threshold uncertainty score0.091

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0020.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.002
Science and technology studies0.0010.001
Scholarly communication0.0020.002
Open science0.0010.002
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0270.047

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.237
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2007
Admission routes1
Has abstractyes

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Same venueKirk-Othmer Encyclopedia of Chemical TechnologySame topicProcess Optimization and IntegrationFrench-language works237,207