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Preface

2003· book-chapter· en· W183445174 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueCambridge University Press eBooks · 2003
Typebook-chapter
Languageen
FieldChemistry
TopicMolecular Spectroscopy and Structure
Canadian institutionsnot available
Fundersnot available
KeywordsComputer science

Abstract

fetched live from OpenAlex

A book whose title refers to the spectroscopy of diatomic molecules is, inevitably, going to be compared with the classic book written by G. Herzberg under the title Spectroscopy of Diatomic Molecules. This book was published in 1950, and it dealt almost entirely with electronic spectroscopy in the gas phase, studied by the classic spectrographic techniques employing photographic plates. The spectroscopic resolution at that time was limited to around 0.1 cm−1 by the Doppler effect; this meant that the vibrational and rotational structure of electronic absorption or emission band systems could be easily resolved in most systems. The diatomic molecules studied by 1950 included conventional closed shell systems, and a large number of open shell electronic states of molecules in both their ground and excited states. Herzberg presented a beautiful and detailed summary of the principles underlying the analysis of such spectra. The theory of the rotational levels of both closed and open shell diatomic molecules was already well developed by 1950, and the correlation of experimental and theoretical results was one of the major achievements of Herzberg's book. It is a matter of deep regret to us both that we cannot present our book to ‘GH’ for, hopefully, his approval. On the other hand, we were both privileged to spend time working in the laboratory in Ottawa directed by GH, and to have known him as a colleague, mentor and friend.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.946
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.001
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.187
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it