MétaCan
Menu
Back to cohort
Record W1862762058 · doi:10.1002/9780470027318.a6011

Isotope Ratio Mass Spectrometry

2000· other· en· W1862762058 on OpenAlexaff
H. R. Krouse

Bibliographic record

VenueEncyclopedia of Analytical Chemistry · 2000
Typeother
Languageen
FieldEnvironmental Science
TopicIsotope Analysis in Ecology
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsIsotope-ratio mass spectrometryIsotopeMass spectrometryAnalytical Chemistry (journal)ChemistryStable isotope ratioEnvironmental chemistryNuclear physicsPhysicsChromatography

Abstract

fetched live from OpenAlex

Abstract With the separation of two of the three stable isotopes of neon by Sir J.J. Thomson in 1913, mass spectrometers have continued to be the instrument of choice for measuring ratios of isotope abundances. The first magnetic sector mass spectrometer specifically dedicated to this task was designed by A.O. Nier in 1947 and featured simultaneous collection of ion currents. Many diverse instruments have evolved from this design. Decades of development of sample preparation techniques have realized isotope ratio data from many elements in solids, liquids, and gases. Coupling of devices such as gas chromatographs, combustion apparati, and laser probes to mass spectrometers in concert with computer control, have realized features such as unattended operation, compound‐specific isotope analyses and isotopic data spatially resolved over distances of a few micrometers on solid surfaces. Today, applications of isotope ratio mass spectrometry (IRMS) embrace many disciplines with topics such as paleodiets, food adulteration, paleoclimatology, migration of birds and animals, pollutant tracing, ore and oil deposits, meteorology, energy expenditure of animals, including astronauts, and the origin of the universe.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.458
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.4600.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.220
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2000
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Analytical ChemistrySame topicIsotope Analysis in EcologyFrench-language works237,207