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Record W1876373815 · doi:10.1029/2003gb002152

Speciation and fluxes of nutrients (N, P, Si) from the upper Yukon River

2004· article· en· W1876373815 on OpenAlexaboutno aff
Laodong Guo, Jia‐Zhong Zhang, Céline Guéguen

Bibliographic record

VenueGlobal Biogeochemical Cycles · 2004
Typearticle
Languageen
FieldEnvironmental Science
TopicSoil and Water Nutrient Dynamics
Canadian institutionsnot available
FundersCold Regions Research and Engineering Laboratory
KeywordsNutrientParticulatesEnvironmental chemistryFlux (metallurgy)Genetic algorithmDissolved organic carbonChemistryEnvironmental scienceHydrology (agriculture)GeologyEcologyBiology

Abstract

fetched live from OpenAlex

Water samples were collected from the Yukon River near the Stevens Village Station from May to September 2002 and analyzed for nutrients (N, P, and Si) in dissolved, particulate, organic, and inorganic forms to examine temporal variations in nutrient concentrations, fluxes, and phase partitioning. Both NO3 and PO4 concentrations in the Yukon River were much lower than those of world rivers, with an average concentration of 2.43 ± 0.63 μM‐N and 0.053 ± 0.040 μM‐P, respectively. Si(OH)4 concentrations were more comparable to those of world rivers, with an average concentration of 82 ± 21 μM‐Si. Integrated annual fluxes were 2.4 × 108 mole‐NO3, 3.4 × 106 mole‐PO4, and 8.7 × 109 mole‐Si(OH)4, respectively. Nutrient discharge during the river ice open season contributed 73 to 95% of the annual flux depending on nutrient species. Within the total N pool transported by the Yukon River, dissolved inorganic N comprised 7 ± 4% and particulate N made up 25 ± 10%, while dissolved organic N (DON) was the dominant N species (with an average of 67 ± 10%). In contrast, P was predominantly partitioned in the particulate phase (with an average of 94 ± 6%), leaving 4 ± 5% of the total P in the dissolved organic phase and ∼2 ± 1% in the dissolved inorganic phase. The partitioning of N and P indicates that the transformation between dissolved and particulate or inorganic and organic phases may play a critical role in controlling the flux of bioavailable nutrients and thus the nutrient dynamics in the Yukon River Basin and its coastal region. Nutrient specific fluxes normalized to drainage area in the Yukon River Basin were 0.57 mmole/m2/yr for NO3, 0.012 mmole/m2/yr for PO4, and ∼19 mmole/m2/yr for Si(OH)4, respectively. The relatively low specific fluxes of NO3 and PO4 in the Yukon River Basin reflect its pristine status or little anthropogenic influence, whereas cold climate in the Arctic/subarctic region may be responsible for its lower Si(OH)4 specific flux, in agreement with a general trend of increasing Si specific flux with decreasing latitude in global river systems. A warming climate and thus deeper permafrost active layer in the Yukon River watershed would likely enhance the export flux of nutrients into the Bering Sea.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.220
Threshold uncertainty score0.437

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.201
Teacher spread0.196 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations123
Published2004
Admission routes1
Has abstractyes

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