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Record W1881390664 · doi:10.1039/c5cs00365b

Group 14 inorganic hydrocarbon analogues

2015· review· en· W1881390664 on OpenAlexaff
Eric Rivard

Bibliographic record

VenueChemical Society Reviews · 2015
Typereview
Languageen
FieldChemistry
TopicSynthesis and characterization of novel inorganic/organometallic compounds
Canadian institutionsAlberta Hospital EdmontonUniversity of Alberta
Fundersnot available
KeywordsHydrocarbonGroup (periodic table)Reactivity (psychology)ChemistryMain group elementOrganic chemistryNanomaterialsNanotechnologyMaterials scienceCombinatorial chemistryChemical engineeringCatalysisTransition metalEngineering

Abstract

fetched live from OpenAlex

Hydrocarbons are ubiquitous in our daily lives due to their use as commodity materials (e.g. polyethylene) and fuels. Heavier Group 14 element hydrides, termed herein as "inorganic hydrocarbon analogues", often exhibit divergent reactivity with respect to their organic congeners. In addition to expanding our general knowledge with respect to periodic trends, inorganic Group 14 hydrides have a prominent role in industry as gaseous, and now liquid-phase, precursors to semi-conducting films; furthermore, these species have been successfully used to prepare nanomaterials of controllable shape and function. This Review covers these exciting fields of study along with providing computationally-derived insights from the literature as they pertain to the reactivity and structural diversity of inorganic hydrocarbon analogues (118 references).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.963
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0050.003
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.077
GPT teacher head0.306
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations122
Published2015
Admission routes1
Has abstractyes

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