PEGylation of Chitosan Via Nitroxide‐Mediated Polymerization in Aqueous Media
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The PEGlytation of CTS with poly(poly(ethyleneglycol) methyl ether methacrylate‐co‐styrene), poly(PEGMA‐co‐S), via nitroxide‐mediated polymerization (NMP) using both grafting to and from approaches has been performed. To conduct the PEGylation of CTS via grafting to, CTS was first functionalized with glycidyl methacrylate (GMA) yielding CTS‐ g ‐GMA macromer. Poly(PEGMA‐co‐S), synthesized via NMP, was then grafted to the CTS‐ g ‐GMA. For PEGylation via grafting from, CTS‐ g ‐GMA was first converted into a macroalkoxyamine using an SG1‐based alkoxyamine. Graft copolymerization of PEGMA‐co‐S was then performed. The syntheses of CTS‐ g ‐GMA‐poly(PEGMA‐co‐S) were confirmed by 1 H NMR and TGA.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it