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Record W1914777325 · doi:10.1002/047084289x.rn01411

Bicyclo[2.2.1]hepta-2,5-diene (Norbornadiene)

2012· reference-entry· en· W1914777325 on OpenAlexaff
Tanner J. Kettles, William Tam

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2012
Typereference-entry
Languageen
FieldChemistry
TopicAsymmetric Synthesis and Catalysis
Canadian institutionsUniversity of Guelph
Fundersnot available
KeywordsNorbornadieneOxidizing agentChemistryReagentSolubilityDieneCatalysisDistillationOrganic chemistryNuclear chemistryMedicinal chemistry

Abstract

fetched live from OpenAlex

[121-46-0] C7H8 (MW 92.14) InChI = 1S/C7H8/c1-2-7-4-3-6(1)5-7/h1-4,6-7H,5H2 InChIKey = SJYNFBVQFBRSIB-UHFFFAOYSA-N (reagent used in a variety of cycloadditions, addition reactions, and as ligand in metal catalysis) Alternate Name: norbornadiene. Physical Data: mp −19.1 °C; bp 89 °C; 0.906 g cm−3. Solubility: most organic solvents. Form Supplied in: colorless liquid; widely available. Purification: purified by distillation from activated alumina. Handling, Storage, and Precautions: highly flammable, avoid exposure to heat, flame, and spark. Store under an inert gas and refrigerate; avoid prolonged exposure to light. Norbornadiene has mild oral and inhalation toxicity; it should be worked within a well-ventilated area. Toxicity, LD50 (oral, mouse) 3850 mg kg−1; LC50 (inhalation, rat, 8 h) 14 100 ppm. Incompatible with strong acids, strong bases, and strong oxidizing agents.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.050
Threshold uncertainty score0.169

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0500.020

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.238
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2012
Admission routes1
Has abstractyes

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