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Record W1932235611 · doi:10.1039/c5cp03668b

Luminescence and X-ray absorption studies on 0.5% Ce<sup>3+</sup> doped BaCa<sub>2</sub>MgSi<sub>2</sub>O<sub>8</sub> phosphor

2015· article· en· W1932235611 on OpenAlexafffund
Dejian Hou, Weijie Zhou, Cen Wu, P. Dorenbos, H. Liang, Tsun‐Kong Sham, Bingbing Zhang, Yan Huang, Ye Tao

Bibliographic record

VenuePhysical Chemistry Chemical Physics · 2015
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence Properties of Advanced Materials
Canadian institutionsWestern University
FundersChina Scholarship CouncilNatural Sciences and Engineering Research Council of CanadaNational Natural Science Foundation of ChinaCanadian Light Source
KeywordsPhosphorCeriumLuminescenceXANESDopingAnalytical Chemistry (journal)Absorption (acoustics)Absorption edgeIonMaterials scienceAbsorption spectroscopyExcitationFluorescenceChemistrySpectral lineInorganic chemistryOpticsOptoelectronicsPhysicsBand gap

Abstract

fetched live from OpenAlex

0.5% Ce(3+) doped BaCa2MgSi2O8 phosphor was prepared by a conventional solid state reaction method. Luminescence spectra as well as fluorescence decay were monitored in the VUV-UV range. Ce(3+) emissions are assigned to cerium ions on a Ba(2+) site, and the five 4f-5d excitation bands of Ce(3+) were determined at low temperature. The light yield is estimated to be around 10,600 ph MeV(-1) under X-ray excitation. X-ray absorption near-edge structure (XANES) was explored to study the energy transfer efficiency to optical centers from each element in the phosphor; the results show that the contributions to luminescence are not identical for each element.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.000
Bibliometrics0.0000.001
Science and technology studies0.0000.002
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.256
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations18
Published2015
Admission routes2
Has abstractyes

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