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Record W1938344552 · doi:10.1039/c4tb01504e

Structure and solubility behaviour of zinc containing phosphate glasses

2015· article· en· W1938344552 on OpenAlexafffund
Nasima Kanwal, Harold Toms, Alex C. Hannon, Frédéric A. Perras, David L. Bryce, Natalia Karpukhina, Isaac Abrahams

Bibliographic record

VenueJournal of Materials Chemistry B · 2015
Typearticle
Languageen
FieldMaterials Science
TopicGlass properties and applications
Canadian institutionsUniversity of Ottawa
FundersScience and Technology Facilities CouncilEngineering and Physical Sciences Research CouncilRoyal Society of ChemistryQueen Mary University of LondonRoyal SocietyUniversity of OttawaOntario Innovation Trust
KeywordsSolubilityZinc phosphateZincPhosphateMaterials scienceChemical engineeringInorganic chemistryMetallurgyChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Zn NMR and neutron diffraction analysis confirming zinc exhibits predominantly four-coordinate geometry. Solubility in deionised water and tris/HCl buffer solution is seen to decrease significantly with increasing x-value. This is discussed in terms of water ingress and the degree of structural openness, associated with increased cross-linking and a decrease in concentration of P-O-P linkages. pH measurements confirm invert phosphate compositions maintain physiological pH levels on immersion in water and buffer solutions for up to four weeks.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.451

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.257
Teacher spread0.233 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations27
Published2015
Admission routes2
Has abstractyes

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