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Record W1963404397 · doi:10.1149/1.2949405

Phases Formed in Al-Doped Ni[sub 1/3]Mn[sub 1/3]Co[sub 1/3](OH)[sub 2] Prepared by Coprecipitation: Formation of Layered Double Hydroxide

2008· article· en· W1963404397 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueJournal of The Electrochemical Society · 2008
Typearticle
Languageen
FieldMaterials Science
TopicLayered Double Hydroxides Synthesis and Applications
Canadian institutionsDalhousie University
FundersNatural Sciences and Engineering Research Council of CanadaDalhousie University
KeywordsCoprecipitationHydroxideLayered double hydroxidesThermogravimetric analysisPhase (matter)CalcinationMaterials scienceAnalytical Chemistry (journal)IonDopingInorganic chemistryGravimetric analysisChemistryCatalysisChromatography

Abstract

fetched live from OpenAlex

The coprecipitation process, using either mixed nitrate or sulfate solutions, to produce Al-doped has been studied in detail. Using X-ray diffraction (XRD) and thermal gravimetric analysis (TGA), it has been determined that charge-compensating or ions accompany the incorporated ions into the structure to form layered double hydroxides (LDHs). The phases formed were determined for in and . For , two phase mixtures between (, Mn, and Co) and the LDH phase with were formed. For aluminum contents greater than , XRD and TGA experiments suggest that the excess Al is present as and that the product is a mixture of or and , where M represents the mixture of Ni, Mn, and Co. Alternatively, the data can also be explained assuming that samples with are single phase . TGA experiments show that the in the -containing LDH is eliminated at lower temperature than the in the -containing LDH. Thus coprecipitations using nitrates may be preferred in situations where excellent cation mixing is desired in the production of Al-doped .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.032
Threshold uncertainty score0.862

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.260
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it