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Record W1963829504 · doi:10.1021/ie020094g

Reconciliation Procedure for Gas−Liquid Interfacial Area and Mass-Transfer Coefficient in Randomly Packed Towers

2002· article· en· W1963829504 on OpenAlexafffund
Simon Piché, Bernard P. A. Grandjean, Faı̈çal Larachi

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2002
Typearticle
Languageen
FieldEnvironmental Science
TopicGroundwater flow and contamination studies
Canadian institutionsUniversité Laval
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMass transferMass transfer coefficientCorrelation coefficientChemistryThermodynamicsTransfer (computing)Approximation errorTowerArtificial neural networkAnalytical Chemistry (journal)StatisticsMathematicsChromatographyPhysicsComputer scienceStructural engineering

Abstract

fetched live from OpenAlex

Interfacial areas ( a w ) and volumetric mass-transfer coefficients ( k L a w, K L a w, k G a w, and K G a w ) required for randomly packed tower design were gathered from the literature to generate a working database including over 3780 measurements. A set of artificial neural network correlations for the gas−liquid interfacial area and the pure local mass-transfer coefficients was proposed. Thus, the gas−liquid interfacial area and the pure local mass-transfer coefficients ( k γ, where γ = G or L) were extracted using a reconciliation procedure which combined actually measured interfacial areas with pseudo interfacial areas inferred from the actually measured volumetric mass-transfer coefficients. The neural network weights of the two a w and k γ correlations were adjusted using a least-squares composite criterion simultaneously over the five mass-transfer parameters. The first correlation representing the gas−liquid interfacial area [ a w / a T = f ( Re L, Fr L, Eo L,χ, K )] yielded an average absolute relative error (AARE) of 22.5% for the 325 measurements available. The second one, representing either k G or k L, was also implemented using the following structure: Sh γ = f ( Re γ, Fr γ, Sc γ,χ). The combination of both correlation predictions (i.e., k γ a w ) yielded an AARE of 24.4% for the local and global volumetric mass-transfer coefficients (3455 data).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.115
Threshold uncertainty score0.510

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.074
GPT teacher head0.276
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations31
Published2002
Admission routes2
Has abstractyes

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