Absorption spectroscopic study of the conduction band of titanium dichalcogenides
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Bibliographic record
Abstract
The L 2, 3 spectra of titanium in the layered compound TiSe2 and intercalated compounds Fe1/2TiSe2, Cr1/3TiSe2, and Fe1/4TiTe2 are studied. Theoretical calculations of the electronic structure of these compounds are performed. The experimental data and calculations suggest that the intercalation of the Cr and Fe atoms into the TiSe2 matrix brings about a partial filling of the Ti 3d states and the spin polarization of the Cr 3d and Fe 3d states. Chemical bonds are formed through the hybridization of the d orbitals of intercalated atoms with the Ti 3d-Se 4p states of the matrix.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it