Syntheses, Structures, and Luminescence/Electroluminescence of BPh<sub>2</sub>(mqp), Al(CH<sub>3</sub>)(mqp)<sub>2</sub>, and Al(mqp)<sub>3</sub> (mqp = 2-(4‘-Methylquinolinyl)-2-phenolato)
Bibliographic record
Abstract
Three new complexes BPh 2 (mqp) ( 1 ), Al(CH 3 )(mqp) 2 ( 2 ), and Al(mqp) 3 ( 3 ) have been synthesized and characterized, where mqp = 2-(4‘-methylquinolinyl)-2-phenolato. The mqp ligand in compounds 1 and 2 act as a chelate ligand, while in compound 3 it acts as both a chelate ligand and a terminal ligand. The boron center in 1 has tetrahedral geometry, while the aluminum ion in 2 and 3 has trigonal-bipyramidal geometry. In CH 2 Cl 2 solution, these compounds emit a green, a green-blue, and a whitish blue color (λ = 514, 515, 497 nm), respectively, when irradiated by UV light. In the solid state, these three compounds emit a green, a blue, and a whitish blue color, respectively (λ = 520, 474, 500 nm). Electroluminescent devices using compound 3 as an emitter have been fabricated.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.001 |
| Meta-epidemiology (narrow) | 0.003 | 0.003 |
| Meta-epidemiology (broad) | 0.003 | 0.001 |
| Bibliometrics | 0.002 | 0.004 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.002 | 0.001 |
| Research integrity | 0.001 | 0.003 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".