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Record W1965000755 · doi:10.1139/v10-153

Efficient process for the conversion of xylose to furfural with acidic ionic liquid

2011· article· en· W1965000755 on OpenAlexvenueno aff
Furong Tao, Huanling Song, Lingjun Chou

Bibliographic record

VenueCanadian Journal of Chemistry · 2011
Typearticle
Languageen
FieldEngineering
TopicCatalysis for Biomass Conversion
Canadian institutionsnot available
FundersState Key Laboratory for Oxo Synthesis and Selective Oxidation
KeywordsFurfuralChemistryXyloseYield (engineering)Ionic liquidCatalysisHydrogen SulfateSulfonic acidOrganic chemistryDehydrationInorganic chemistryFermentationBiochemistry

Abstract

fetched live from OpenAlex

An efficient and simple process for the dehydration of xylose into furfural was studied, which was catalyzed by 1-(4-sulfonic acid)butyl-3-methylimidazolium hydrogen sulfate (IL-1) under mild conditions. A xylose conversion of 95.3% with a furfural yield of 91.45% was achieved in a 25 min reaction time at 150 °C; the xylose conversion and furfural yield greatly depended on the operation conditions, such as reaction time and temperature. IL-1 could be recycled and exhibited constant activity for five successive trials. This system was an important improvement, relative to the reactions using mineral acids at high temperatures, for further development on a pilot scale.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.184
Teacher spread0.174 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations43
Published2011
Admission routes1
Has abstractyes

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