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Record W1965326024 · doi:10.1103/physrevb.65.041401

<i>Ab initio</i><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>I</mml:mi><mml:mo>−</mml:mo><mml:mi>V</mml:mi></mml:math>characteristics of short<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mml:mrow><mml:mn>20</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>chains

2001· article· lv· W1965326024 on OpenAlexafffund
Christopher Roland, Brian Larade, Jeremy Taylor, Hong Guo

Bibliographic record

VenuePhysical review. B, Condensed matter · 2001
Typearticle
Languagelv
FieldEngineering
TopicMolecular Junctions and Nanostructures
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of CanadaU.S. Department of Energy
KeywordsAb initioFormalism (music)PhysicsMoleculeOrientation (vector space)Ab initio quantum chemistry methodsCrystallographyMaterials scienceAtomic physicsChemistryQuantum mechanicsGeometry

Abstract

fetched live from OpenAlex

We have calculated the $I\ensuremath{-}V$ characteristics of short chains of ${\mathrm{C}}_{20}$ molecular cages between $\mathrm{Al}$ and $\mathrm{Au}$ leads with an ab initio formalism. The results indicate that a linear chain of such molecules acts primarily as metallic nanowires. The transmission, however, depends sensitively both on the orientation and distance between the individual ${\mathrm{C}}_{20}$ molecules. Transport through the molecular chains is accompanied by a significant amount of charge transfer, which remains localized at the electrode/molecular interface.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.003
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.796
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0030.003
Meta-epidemiology (narrow)0.0020.004
Meta-epidemiology (broad)0.0010.005
Bibliometrics0.0010.002
Science and technology studies0.0020.003
Scholarly communication0.0020.002
Open science0.0040.003
Research integrity0.0040.004
Insufficient payload (model declined to judge)0.2670.007

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.244
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations38
Published2001
Admission routes2
Has abstractyes

Explore more

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