Photocontrolled oscillatory dynamics in the bromate-1,4-cyclohexanedione reaction
Bibliographic record
Abstract
We report observations of photocontrolled oscillatory behavior in the 1,4-cyclohexanedione- bromate reaction (CHD—cyclohexanedione). Experiments in a batch reactor show that illumination may exhibit qualitatively different effects on the reaction dynamics, where illumination with a moderate intensity favors oscillations while strong illumination quenches spontaneous oscillations. A transition from light-quenched to light-induced oscillations during the course of the reaction has also been observed. Investigations in a continuous flow stirred tank reactor further illustrate that the influence of light in the 1,4-CHD-bromate reaction depends not only on the intensity of the illumination but also on the phase at which the illumination is switched on. Mechanistic investigations suggest that 1,4-benzoquinone, a final product in the 1,4-CHD-bromate reaction system, plays a significant role in the occurrence of photoinduced oscillations.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".