Formation of hybrid micelles between poly(ethylene glycol)-block-poly(4-vinylpyridinium) cations and sulfate anions in an aqueous milieu
Bibliographic record
Abstract
The SO-induced micellization of poly(ethylene glycol)--poly(4-vinylpyridinium)(PEG-b-P(4-VPH)) in aqueous solution is studied by dynamic and static light scattering, and transmission electron microscopy. The SO anions can act as cross-linkers of the P(4-VPH) blocks through the electrostatic attraction between 4-VPH and SO to induce the micellization of PEG--P(4-VPH). The resultant hybrid micelles are spherical and consist of an ion-complex core of P(4-VPH)/SO and a water-soluble PEG corona and present a density gradient between the core and corona and the core has a higher density. The SO concentrations can affect the structure of the core-corona hybrid micelles. The low SO conentration leads to a loose core while the high SO concentration leads to a compact core.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".