Surface-Enhanced Raman Scattering of the Bariandite Oxide Layer on a Vanadium Dioxide Crystal
Bibliographic record
Abstract
Variable-temperature (25–100°C) Raman spectra of a crystal of commercial VO2 have revealed surface-enhanced Raman scattering (SERS) of the V=O stretching mode of the bariandite-like vanadium oxide species, V10O24·9H2O, that is formed on the surface of the crystal. Upon passing through the semiconductor-to-metal phase transition of VO2 at 68°C, there is an approximately three to five-fold increase in Raman intensity of the V=O stretching mode. This effect is reversible with hysteresis upon decreasing the temperature. The temperature dependence of the Raman spectra at temperatures below the transition suggest that even the semiconductor phase has some SERS effect.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".