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Record W1966595048 · doi:10.1021/ef049792z

Interfacial Interactions between Reservoir Brine and CO<sub>2</sub>at High Pressures and Elevated Temperatures

2004· article· en· W1966595048 on OpenAlex
Daoyong Yang, Paitoon Tontiwachwuthikul, Yongan Gu

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueEnergy & Fuels · 2004
Typearticle
Languageen
FieldEnvironmental Science
TopicCO2 Sequestration and Geologic Interactions
Canadian institutionsPetroleum Technology Research CentreUniversity of Regina
FundersNatural Sciences and Engineering Research Council of CanadaPetroleum Technology Research Centre
KeywordsBrineSolubilityWettingChemistrySurface tensionDrop (telecommunication)SwellingThermodynamicsMaterials scienceComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

In this paper, an experimental technique has been developed to study the interfacial interactions of the reservoir brine−CO 2 system at high pressures and elevated temperatures. Using the axisymmetric drop shape analysis (ADSA) for the pendant drop case, this new technique makes it possible to determine the interfacial tension (IFT) and visualize the interfacial interactions between the reservoir brine and CO 2 under practical reservoir conditions. More specifically, the dynamic IFT between the reservoir brine and CO 2 is measured as a function of pressure at two different temperatures. It is found that the dynamic IFT gradually reduces to a constant value, which is termed as the equilibrium IFT. The equilibrium IFT decreases as the pressure increases, whereas the same parameter increases as the temperature increases. The major interfacial interactions observed in this study include interface disappearance, the swelling effect, the shrinking effect, and wettability alteration. At an elevated temperature ( T = 58 °C), the pendant brine drop cannot be observed in the CO 2 phase at a pressure of P ≥ 12.238 MPa. It is also found that CO 2 solubility in the brine phase, which is measured using the PVT system, approaches its maximum value under the same conditions. Further increases in pressure do not noticeably increase the CO 2 solubility in the brine phase. The brine swelling effect is observed at all the pressures and temperatures tested, whereas the brine shrinking effect occurs only at high pressures and a lower temperature ( T = 27 °C). In addition, the wettability of the reservoir brine−CO 2 system changes from the hydrophilic case to the hydrophobic case when the CO 2 changes from the gas phase to the liquid phase.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.193
Threshold uncertainty score0.884

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.246
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it