Bis(tetraphenylphosphonium) tris(oxalato-<i>O</i>,<i>O</i>′)germanate(IV)
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The synthesis and structure of the title compound, (C(24)H(20)P)(2)[Ge(C(2)O(4))(3)], are reported. The PPh(4)(+) cations in the structure form infinite zigzag chains in which the P.P distances alternate between 6.229 (1) and 7.118 (1) A, and the P.P.P angle is 131.4 (1) A. The shorter P.P distance is associated with a sixfold phenyl embrace. However, the longer P.P distance is associated with both phenyl-phenyl interactions and interactions between the cations and a twofold symmetric [Ge(C(2)O(4))(3)](2-) anion. In the cation-anion interactions, the P.O distance is 4.444 (2) A, the O.P-C(distal) angle is 175.0 (1) degrees and the shortest H.O distances are 2.74 and 3.09 A.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.001 | 0.003 |
| Science and technology studies | 0.002 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.004 | 0.001 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.005 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it