Improved Syntheses of Versatile Ruthenium Hydridocarbonyl Catalysts Containing Electron‐Rich Ancillary Ligands
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Clean, high‐yield routes are established to the important catalyst chlorobis(tricyclohexylphosphine)ruthenium hydridocarbonyl [RuHCl(CO)(PCy 3 ) 2 ] 2 and its N‐heterocyclic carbene (NHC) derivatives RuHCl(CO)(NHC)(PCy 3 ) ( 3a : NHC=IMes; 3b , NHC=H 2 IMes; IMes=1,3‐dimesitylimidazol‐2‐ylidene). These complexes are obtained by treating chlorotris(tricyclohexylphosphine)ruthenium hydridocarbonyl [RuHCl(CO)(PPh 3 ) 3 ] 1 with tricyclohexylphosphine [PCy 3 ], or with the appropriate NHC ligand, then PCy 3 . Advantages over prior routes to these complexes lie in the high yields from a conveniently accessible precursor, the absence of by‐products that otherwise prove difficult to remove, and the short reaction times under experimentally convenient conditions.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.006 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it