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Record W1967099078 · doi:10.1002/cjce.5450830225

The Correlation and Prediction of Butane/Water and Gas/Butane Partition Coefficients

2008· article· en· W1967099078 on OpenAlexvenueno aff
Michael H. Abraham, William E. Acree

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2008
Typearticle
Languageen
FieldChemical Engineering
TopicChemical and Physical Properties in Aqueous Solutions
Canadian institutionsnot available
Fundersnot available
KeywordsButanePartition coefficientChemistryCorrelation coefficientThermodynamicsSolvationChromatographyPhysicsMathematicsOrganic chemistryIon

Abstract

fetched live from OpenAlex

It has been pointed out previously that the butane/water partition coefficient is a key parameter in the determination of extraction affinity. We have taken 43 such partition coefficients and have obtained a very satisfactory correlation with Abraham solvation parameters. Similarly, we have obtained a good correlation of 43 gas/butane partition coefficients. These correlations are general, and can be used to predict further values of the butane/water and gas/butane partition coefficient. Des études précédentes ont montré que le coefficient de séparation butane/eau est un paramètre clé dans la détermination de l'affinité de l'extraction. Nous avons pris 43 de ces coefficients de séparation et obtenu une corrélation très satisfaisante avec des paramètres de solvatation d'Abraham. De la même manière, nous avons obtenu une bonne corrélation des 43 coefficients de séparation gaz/butane. Ces corrélations sont générales et peuvent permettre de prédire d'autres valeurs du coefficient de séparation butane/eau et gaz/butane.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.343
Threshold uncertainty score0.218

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.165
Teacher spread0.155 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2008
Admission routes1
Has abstractyes

Explore more

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