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Record W1968866562 · doi:10.1016/j.egypro.2012.09.060

Photocatalytic Hydrogen Production in a UV-irradiated Fluidized Bed Reactor

2012· article· en· W1968866562 on OpenAlexaff
Kevin Reilly, Fariborz Taghipour, David P. Wilkinson

Bibliographic record

VenueEnergy Procedia · 2012
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsPhotocatalysisSlurryFluidized bedTitanium dioxideHydrogen productionIrradiationMaterials scienceHydrogenChemical engineeringMass transferWaste managementCatalysisChemistryChromatographyComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

Since the discovery of photocatalytic watersplitting over titanium dioxide (TiO 2 ), researchers have typically only employed immobilized-film and suspended slurry photocatalysts. Here we present watersplitting in a UV- irradiated fluidized bed reactor with a novel, fluidizable watersplitting photocatalyst. This approach was taken to address the mass-transfer effects, poor radiation distribution, parasitic back-reaction and photocatalyst handling difficulties that limit the efficiency and scalability of existing watersplitting systems. Using a 2.2 M Na 2 CO 3 solution, significant hydrogen production rates were achieved. A marked increase in the hydrogen production rate was observed when compared to results obtained by a suspended slurry TiO 2 photocatalyst in the same reactor.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.025
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.253
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations17
Published2012
Admission routes1
Has abstractyes

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