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Record W1970307966 · doi:10.1039/c3em00385j

Model-based exploration of the drivers of mountain cold-trapping in soil

2013· article· en· W1970307966 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueEnvironmental Science Processes & Impacts · 2013
Typearticle
Languageen
FieldEnvironmental Science
TopicToxic Organic Pollutants Impact
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsDeposition (geology)Atmosphere (unit)Soil waterTrappingEnvironmental sciencePrecipitationSnowPollutantParticle (ecology)FugacityAtmospheric sciencesChemistryEnvironmental chemistryHydrology (agriculture)Soil scienceMeteorologyGeologyGeomorphologySedimentEcology

Abstract

fetched live from OpenAlex

A pollutant is said to undergo mountain cold-trapping if it is found at higher concentrations in a surface medium (soil, snow, foliage) high on a mountain, where it is colder, than in the same medium lower on the mountain. The processes that lead to mountain cold-trapping in soil were explored for a set of hypothetical Perfectly Persistent Pollutants (PPPs) by varying several environmental parameters in a fugacity based fate and transport box model. These parameters were: the spatial scale of the mountain; the rate and location of rain; the amount of particles in the atmosphere; the presence and magnitude of the upslope temperature gradient. The relative potential of each hypothetical PPP to exhibit mountain cold-trapping was expressed in terms of its Mountaintop Contamination Potential (MCP). The PPPs with the highest MCPs were those that neither were deposited from the atmosphere to the surface in the lower zones in the model nor left the model domain without being deposited at all. The simulations revealed that under most conditions wet-gaseous deposition is the biggest driver of mountain cold-trapping in soils, and its effects are greatly enhanced by large negative temperature gradients and increased precipitation upslope. Dry-gaseous and wet-and-dry-particle deposition processes cause similar PPPs to exhibit mountain cold-trapping, and the contributions to MCP by the dry processes are of the same magnitude as wet-particle deposition. Dry gaseous deposition alone is insufficient to cause mountain cold-trapping in soils under any conditions modelled here. Those measuring organic contaminants in mountains should expect to find that mountains with different climates cold-trap different pollutants, and that some mountains may not exhibit upslope enrichment of any species.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.215
Threshold uncertainty score0.751

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.002
Scholarly communication0.0000.002
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.223
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it