Acid−Base Equilibria of Weak Polyelectrolytes in Multilayer Thin Films
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Bibliographic record
Abstract
In this paper, we report on the local apparent dissociation constants of poly(acrylic acid) and poly(allylamine hydrochloride) incorporated in polyelectrolyte multilayer thin films. We assembled 10 polyelectrolyte layers on colloidal silica by the sequential electrostatic adsorption of the polyacid and polybase from aqueous solutions at different pH values and then measured the zeta potential as a function of the solution pH to determine the p K a(app) of each surface layer. The results suggest that the dissociation constant decreases upon adsorption for poly(acrylic acid) and increases in the case of poly(allylamine hydrochloride). These deviations from ideal behavior can be substantial, changing by as much as 4 pH units, and the shifts become more pronounced as the number of adsorbed layers increases. In addition, we found that these p K a(app) shifts are influenced by the pH of the solution used to assemble the thin films but show little dependence on the salt concentration used in the assembly baths.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it