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Record W1971017512 · doi:10.1021/ma001544o

An Exactly Solvable Ogston Model of Gel Electrophoresis. 7. Diffusion and Mobility of Hard Spherical Particles in Three-Dimensional Gels

2001· article· en· W1971017512 on OpenAlexafffund
Jean‐François Mercier, Gary W. Slater

Bibliographic record

VenueMacromolecules · 2001
Typearticle
Languageen
FieldMaterials Science
TopicMaterial Dynamics and Properties
Canadian institutionsUniversity of Ottawa
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsExtrapolationLattice (music)Limit (mathematics)DiffusionPhysicsElectrophoresisStatistical physicsChemistryMathematical analysisThermodynamicsMathematicsChromatography

Abstract

fetched live from OpenAlex

We extend our lattice model of gel electrophoresis (and diffusion) to the study of the continuum limit (no lattice effect) for hard spherical particles migrating in periodic and random three-dimensional gels. To reach the continuum limit, the mesh size of the system is progressively decreased until a clear extrapolation to the continuum limit (where the size of the lattice parameter is infinitely small in comparison to the size of the gel fibers) can be done. Various types of gel are studied, starting from simple periodic parallel and straight fibers to a representation of a more realistic gel formed of irregular, cross-linked fibers placed along random directions. Our mobility data for pseudospherical particles in the continuum limit are interpreted in terms of the obstruction model of diffusion.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.265
Threshold uncertainty score0.424

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.230
Teacher spread0.213 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations31
Published2001
Admission routes2
Has abstractyes

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