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Record W1972269436 · doi:10.1021/ef010234j

Quality of Distillates from Repeated Recycle of Residue

2002· article· en· W1972269436 on OpenAlexaff
Shakir Japanwala, Keng H. Chung, Heather D. Dettman, Murray R. Gray

Bibliographic record

VenueEnergy & Fuels · 2002
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsSyncrude (Canada)University of Alberta
Fundersnot available
KeywordsResidue (chemistry)CokeChemistryDistillationNitrogenVacuum distillationChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

The yields of gas, liquid, and coke from the coking of Athabasca vacuum residue were determined as a function of conversion of the residue. High conversion was achieved by subjecting the unconverted residue to repeated coking steps. The cumulative yield of liquid increased by 12% from stage 1 of coking, where 80% residue conversion was obtained, to stage 3 where over 97% cumulative residue conversion was obtained. The quality of the distillates obtained at each stage deteriorated based on the concentrations of nitrogen and polyaromatic hydrocarbons. Although coking reactions resulted in a significant decrease in the number of paraffinic chains, the average chain length remained constant. A mass balance showed that the aromatic carbon increased in the first coking step, then remained constant.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.251
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations51
Published2002
Admission routes1
Has abstractyes

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