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Record W1972372857 · doi:10.1063/1.1585017

Integral equation theories for orientionally ordered fluids

2003· article· en· W1972372857 on OpenAlexaff
Irina Paci, N. M. Cann

Bibliographic record

VenueThe Journal of Chemical Physics · 2003
Typearticle
Languageen
FieldMaterials Science
TopicMaterial Dynamics and Properties
Canadian institutionsQueen's University
Fundersnot available
KeywordsIntegral equationIsotropyLiquid crystalFormalism (music)AnisotropySimple (philosophy)Classical fluidsPhysicsClassical mechanicsStatistical physicsMathematicsMathematical analysisQuantum mechanics

Abstract

fetched live from OpenAlex

Integral equation theories have been quite successful at providing structural information for isotropic fluids. In particular, the expansion method originally proposed by Blum and Torruella [J. Chem. Phys. 56, 303 (1972)] has been pivotal in making these theories feasible for molecular fluids. Recently, integral equation theories have also been applied to nematic phases for simple one-component fluids. In this article, we derive the formalism appropriate for fully, and partially, orientationally anisotropic fluids. Appropriate expansions of the pair and singlet functions are employed to obtain tractable expressions for the three coupled equations which must be solved. The numerical solution of these equations is discussed and simplifications resulting from symmetry are considered in detail. Numerical results are presented for fluids of dipolar ellipsoidal molecules in an external field.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.004
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.002
Scholarly communication0.0020.003
Open science0.0010.001
Research integrity0.0020.002
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.246
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2003
Admission routes1
Has abstractyes

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