Extremely High Degree Photoinduced In-Plane Reorientation in Azobenzene-Containing Polymer Liquid Crystal Film Using 633 nm Light
Bibliographic record
Abstract
The thermally enhanced photoinduced reorientation behavior of liquid crystalline (LC) polymethacrylate films comprising 4-methoxyazobenzene side groups with different spacer lengths between the azobenzene group and the polymer backbone was investigated based on axis-selective Z -to- E photoisomerization using linearly polarized (LP) 633 nm light and thermal amplification of the photoinduced anisotropy. A high-order in-plane reorientation parallel to the polarization (E) of LP 633 nm light was accomplished regardless of the spacer length. We found that the initial orientation of the mesogenic groups played an important role in the reorientation, and clarified the reorientation mechanism by polarization absorption spectroscopy.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".