Determination of Thujone by Derivatization with Dansylhydrazine and Liquid Chromatography
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Bibliographic record
Abstract
Abstract The reaction of α‐ and β‐thujones with dansylhydrazine (DNSH) was studied using reversed phase liquid chromatography (LC) with fluorescence detection. The derivatization procedure, although slow, was applied for determination of α‐thujone in white vermouth at concentrations 0.45–4.5 µg/L using a C18 solid phase extraction column for cleanup; recoveries of added α‐thujone were in the range 60–77%. Separation of dansyl α‐ and β‐thujones was achieved by LC and their identity confirmed by LC‐tandem mass spectrometry (MS/MS). Keywords: Liquid chromatographyDansylhydrazineThujoneVermouth
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it