High‐yield synthesis of milligram amounts of isotopically enriched methylmercury (CH<sub>3</sub><sup>198</sup>HgCl)
Bibliographic record
Abstract
Abstract Isotopically enriched CH3198HgCl (MeHgCl) has been synthesized from commercially available elemental 198Hg (96% isotopic purity). Elemental mercury is first converted to HgCl2 and subsequently reacted with methylcobalamin to produce MeHgCl. The resulting MeHgCl is isolated from the reaction mixture by successive extractions with toluene and dried over Na2SO4. The product structure was verified using gas chromatography–mass spectrometry (GC–MS) and the isotopic composition was determined by GC–inductively coupled plasma MS. The yield obtained is 99%. The proposed method allows preparation of milligram quantities of MeHgCl in one step, minimizing the cost of this synthesis. Copyright © 2004 John Wiley & Sons, Ltd.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".