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Record W1972846853 · doi:10.1021/jp805403e

Compatibility of <i>N</i>-Methyl-<i>N</i>-propylpyrrolidinium Cation Room-Temperature Ionic Liquid Electrolytes and Graphite Electrodes

2008· article· en· W1972846853 on OpenAlexaff
Shiro Seki, Yo Kobayashi, Hajime Miyashiro, Yasutaka Ohno, Yuichi Mita, Nobuyuki Terada, Patrick Charest, Abdelbast Guerfi, Karim Zaghib

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2008
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsHydro-Québec
Fundersnot available
KeywordsElectrolyteIonic liquidGraphiteElectrodeLithium (medication)Inorganic chemistryElectrochemistryIonMaterials scienceMolten saltIonic bondingChemistryAnalytical Chemistry (journal)Organic chemistryPhysical chemistryCatalysisComposite material

Abstract

fetched live from OpenAlex

To realize high-safety, high-performance lithium ion secondary batteries using room-temperature ionic liquids, we examined [graphite electrode|room-temperature ionic liquid−lithium salt binary electrolyte|lithium metal electrode] cells by varying the cation structure of the room-temperature ionic liquid. In particular, a bis(fluorosulfonyl)imide anion based room-temperature ionic liquid cell showed high charge/discharge capacity and reversibility. By application of electrochemical calorimetric measurements during charge/discharge operation, the formation of a suitable interfacial layer, such as a solid electrolyte interphase between the graphite electrode and the room-temperature ionic liquid−lithium salt binary electrolyte was indicated. Moreover, we found that not only the anion structure but also the cation structure was important for the suitable charge/discharge of the graphite electrode.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.374

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.196
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations118
Published2008
Admission routes1
Has abstractyes

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