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Record W1973022978 · doi:10.1063/1.4709995

First-principles study of exohedral and substitutional chemical functionalization of graphene

2012· article· en· W1973022978 on OpenAlexaff
K. Iyakutti, Yoshiyuki Kawazoe

Bibliographic record

VenueAIP conference proceedings · 2012
Typearticle
Languageen
FieldMaterials Science
TopicGraphene research and applications
Canadian institutionsHatch (Canada)
Fundersnot available
KeywordsGrapheneBoronMaterials scienceNitrogenSurface modificationGraphene nanoribbonsMoleculeSiliconChemical physicsBand gapDopingNanotechnologyChemistryOptoelectronicsPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

This first-principles study deals with chemical functionalization of graphene by nitrogen molecule, N2 and electron deficient boron and electron rich nitrogen atoms. The interaction of these chemical species with the graphene lattice is reflected in the electronic structure of graphene. We can obtain p-type and n-type graphene with the substitution of boron and nitrogen atoms respectively. On co-substitution of these atoms, the band gap closes. The results suggest that complementary doping is also applicable for graphene as in silicon.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.324
Threshold uncertainty score0.292

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.057
GPT teacher head0.284
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2012
Admission routes1
Has abstractyes

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