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Record W1973786060 · doi:10.1029/2000jd000260

Airborne CH<sub>2</sub>O measurements over the North Atlantic during the 1997 NARE campaign: Instrument comparisons and distributions

2002· article· en· W1973786060 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2002
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Laser Applications
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsTroposphereEnvironmental scienceAltitude (triangle)Atmospheric sciencesLatitudeSea levelMeteorologyAir mass (solar energy)ClimatologyBoundary layerGeologyGeodesyOceanographyPhysics

Abstract

fetched live from OpenAlex

Airborne CH 2 O measurements were acquired by tunable diode laser absorption spectroscopy (TDLAS) and coil/2,4‐dinitrophenylhydrazine (CDNPH) techniques over remote regions of the North Atlantic Ocean from the surface to 8 km during the North Atlantic Regional Experiment (NARE‐97) in September of 1997. There were eight aircraft flights when both instruments were simultaneously operating, producing 665 overlapping time intervals for comparisons. A number of approaches were used in the comparisons, and indicated that on average both instruments measured identical ambient CH 2 O concentrations to within 0.1 ppbv, and more typically within 0.08 ppbv, over the 0 to 0.8 ppbv‐concentration range. However, significant differences, larger than the combined 2σ total uncertainty estimates, were observed in 29% of the full time‐coincident data set. The two instruments produced very similar altitude trends. Under clean background conditions in the 35° to 55°N latitude band, the median TDLAS and CDNPH CH 2 O concentrations were 0.399 and 0.410 ppbv for 0–2 km, 0.250 and 0.355 ppbv for 2–4 km, and 0.217 and 0.280 ppbv for 4–8 km, respectively. Elevated CH 2 O concentrations were observed in this study at both high altitudes (4–8 km) and in the marine boundary layer by both instruments. Thus vertical transport of CH 2 O and/or its precursors may provide a greater contribution to upper tropospheric HO x than previously thought. The results of this study, which are based upon instruments employing entirely different measurement principles, calibration, and sampling approaches, not only reinforce this conclusion but also provide a high‐quality database necessary to further explore CH 2 O measurement‐model relationships in the clean background atmosphere.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.396
Threshold uncertainty score0.881

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.042
GPT teacher head0.299
Teacher spread0.257 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it