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In Situ XRD and Electrochemical Study of the Reaction of Lithium with Amorphous Silicon

2004· article· en· 1,095 citations· W1974018524 on OpenAlex· 10.1149/1.1739217

Why is this work in the frame?

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

Canadian affiliationAn author listed a Canadian institution. This is the only route the usual frame has.
Canadian funderA Canadian agency funded it. The work may carry no Canadian affiliation at all.

Full frame distilled prediction

Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

Candidate categories
none
Consensus categories
none
Domain
Candidate signal: noneConsensus signal: none
Study design
Candidate signal: Bench or experimentalConsensus signal: Bench or experimental
Genre
Candidate signal: EmpiricalConsensus signal: Empirical
Teacher disagreement score
0.003
Threshold uncertainty score
0.289
Validation status
machine_predicted_unvalidated · codex-gemma-dda1882f352a

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Opus teacher head0.005
GPT teacher head0.218
Teacher spread
0.213 · how far apart the two teachers sit on this one work
Validation status
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Abstract

Silicon is a very promising candidate to replace graphite as the anode in Li-ion batteries because of its very high theoretical capacity. It has not yet made its way into commercial cells because of severe problems with the charge and discharge cycling of the material. It seems that amorphous silicon and amorphous silicon-containing alloys exhibit much improved cycling performance. Therefore, it is desirable to fully understand the reaction of Li with a-Si. To this end, an in situ X-ray diffraction study of the reaction of lithium with a-Si has been performed. The results confirm that a new crystalline phase is formed below 30 mV vs. as first reported by Obrovac and Christensen in an article published in Electrochemical and Solid-State Letters. However, the crystalline phase only forms for films of a-Si above a critical thickness of about 2 μm. © 2004 The Electrochemical Society. All rights reserved.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

The record

Venue
Journal of The Electrochemical Society
Topic
Advancements in Battery Materials
Field
Engineering
Canadian institutions
Dalhousie University
Funders
Natural Sciences and Engineering Research Council of Canada
Keywords
SiliconAmorphous solidElectrochemistryMaterials scienceAnodeLithium (medication)Amorphous siliconGraphiteChemical engineeringCrystalline siliconPhase (matter)NanotechnologyElectrodeMetallurgyCrystallographyChemistryPhysical chemistryOrganic chemistry
Has abstract in OpenAlex
yes