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Record W1974827905 · doi:10.1021/jp013095f

Experiments on Flow-Distributed Oscillations in the Belousov−Zhabotinsky Reaction

2002· article· en· W1974827905 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Physical Chemistry A · 2002
Typearticle
Languageen
FieldComputer Science
TopicNonlinear Dynamics and Pattern Formation
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsWavelengthMechanicsOscillation (cell signaling)PhysicsFlow velocityPhase velocityFlow (mathematics)InflowStanding waveForcing (mathematics)Velocity gradientOpticsChemistryAtmospheric sciences

Abstract

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This paper presents an overview of the waves and patterns that are formed when the oscillatory Belousov−Zhabotinsky medium flows through a packed bed reactor. At a sufficiently high flow velocity, this flow-distributed oscillation (FDO) gives rise to stationary waves with constant forcing at the inflow and to traveling waves with periodic forcing at the inflow. The wavelength of the stationary FDO wave is found to depend on flow velocity and on the effective diffusion coefficient (diameter of packing medium). We demonstrate the breakdown of stationary FDO waves at low flow velocity at which the space-periodic structure is replaced by irregular waves. At high flow velocity, periodic boundary forcing is found to give FDO waves that propagate either with a constant or with an oscillatory velocity. The wavelength and the velocity of the constant velocity upstream or downstream propagating waves are found to agree quantitatively with those predicted theoretically. Finally, we investigate the effect of a frequency gradient on FDO waves. When the oscillation period of the medium increases with the distance from the reactor inlet, it is observed that waves propagate downstream with a decreasing width and velocity. The behavior of both the waves propagating with an oscillatory velocity and those formed in the presence of a frequency gradient can also be understood in terms of phase dynamics.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.827
Threshold uncertainty score0.145

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.256
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it