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Record W1975128251 · doi:10.7901/2169-3358-2008-1-929

AQUEOUS SOLUBILITY, DISPERSIBILITY AND TOXICITY OF BIODIESELS

2008· article· en· W1975128251 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueInternational Oil Spill Conference Proceedings · 2008
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsEnvironment and Climate Change Canada
Fundersnot available
KeywordsBiodieselDaphnia magnaPetroleumDiesel fuelAcute toxicityEnvironmental chemistryEnvironmental scienceChemistryPetroleum productBiofuelPulp and paper industryWaste managementToxicityOrganic chemistry

Abstract

fetched live from OpenAlex

ABSTRACT With increasing interest in the use of plant and animal oils as potential petroleum fuel replacements, there is the potential for accidental release of these biodiesels to the environment. While the behaviours and effects of petroleum diesels have been extensively studied, little is known about either the fate of biofuels in water or their potential effects on aquatic ecosystems. The most important mechanism for exposure of aquatic ecosystems to biodiesels and petroleum diesels is the transfer of material from the non-aqueous phase liquid (NAPL) into the aqueous phase, as both soluble and dispersed components. The equilibrium levels of fuel components in the water, the water-accommodated fractions (WAF) have been measured in fresh water for biodiesels from feedstocks of soy oil, canola oil, waste fry tallow and fish wastes. Biodiesel and petroleum diesels blends of 5% (B5) and 20% (B20) are also measured. Aqueous toxicities are also reported for pure biodiesels and petroleum diesel. Acute toxicities were assessed by 96-hour LC5os of Daphnia magna and rainbow trout and by IC5os of bioluminescent bacteria. The correlations between acute toxicity, WAF concentrations and fuel property data are examined. Natural and chemically-enhanced dispersion of biodiesel is examined in both low- and high-energy conditions. Biodiesels are found to have significant differences with petroleum diesels in water chemistries and in potential ecological impacts. All organisms tested show that biodiesels have less acute toxicity than petroleum diesels. Biodiesels and biodiesel-rich blends were found to be very much more dispersible in high-energy conditions than petroleum diesel.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.110
Threshold uncertainty score0.450

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.233
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it