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Record W1975471568 · doi:10.1021/ma1022814

Isotropic−Nematic Interface in a Lyotropic System of Wormlike Chains with the Onsager Interaction

2010· article· en· W1975471568 on OpenAlexaff
Ying Jiang, Jeff Z. Y. Chen

Bibliographic record

VenueMacromolecules · 2010
Typearticle
Languageen
FieldMaterials Science
TopicLiquid Crystal Research Advancements
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsLiquid crystalLyotropicIsotropyAnisotropyCondensed matter physicsSurface tensionMaterials scienceChemistryPhysicsOpticsThermodynamics

Abstract

fetched live from OpenAlex

The effects of the flexibility of constituent wormlike chains on the interfacial properties between isotropic and nematic phases are investigated in a self-consistent mean-field approximation. The model is built from a wormlike chain formalism which crosses over from the rod limit to the flexible limit, and the Onsager-type interaction which describes the orientation-dependent repulsive interaction. Physical properties such as the surface tension, interfacial width, and density- and order-parameter profiles are numerically calculated as functions of varying flexibility (defined as the ratio between the total polymer length and the persistent length) and tilt angle (defined as the angle between the interfacial normal and the nematic director in the nematic phase). The resulting modified diffusion equation is numerically solved by using a combination of the Crank−Nicolson algorithm and SPHEREPACK, a software package that deals with the analysis and synthesis of spherical-harmonics functions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.329

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.277
Teacher spread0.267 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations39
Published2010
Admission routes1
Has abstractyes

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