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Record W1976415119 · doi:10.1002/masy.200390161

Preparation of synthons for carborane containing macromolecules

2003· article· en· W1976415119 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMacromolecular Symposia · 2003
Typearticle
Languageen
FieldMedicine
TopicBoron Compounds in Chemistry
Canadian institutionsMcMaster University
Fundersnot available
KeywordsCarboraneDendrimerMacromoleculeSynthonMonomerPolymer chemistryChemistryPolyesterAcrylateBiocompatibilityBoronPolymerizationCombinatorial chemistryOrganic chemistryMaterials sciencePolymer

Abstract

fetched live from OpenAlex

Abstract The modification of para ‐carborane with appropriate functionalities for incorporation within a dendrimer framework was accomplished by functionalizing the carbon centers with protected alcohol and free acid groups. These compounds are excellent candidates for utilization as functional linkers between two generations of an aliphatic polyester dendrimer structure. Future assembly of these structures will result in dendritic macromolecules containing carboranes within their interior and will be enveloped by hydrophilic groups (hydroxyls) to maintain their water solubility and biocompatibility. These structures have potential applications in Boron Neutron Capture Therapy and Synovectomy. Additionally, carboranes were coupled to polymerizable acrylate structures, and it was shown that the resulting carborane monomers could be polymerized using living free‐radical polymerization techniques.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.029
Threshold uncertainty score0.891

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.317
Teacher spread0.304 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it