Deuterium NMR and Differential Scanning Calorimetric Studies of the Calcium Salts of Rhodium and Iridium Pentadeuterides, Ca<sub>2</sub>RhD<sub>5</sub> and Ca<sub>2</sub>IrD<sub>5</sub>
Bibliographic record
Abstract
The deuterium NMR spectra of the ternary metal deuterides (TMDs) Ca(2)RhD(5) and Ca(2)IrD(5) show that the disorder is dynamic at room temperature, with barriers to the motion of 31.8 and 39.0 kJ mol(-1), respectively. At low temperatures, splittings equivalent to quadrupole coupling constants of 50.9 and 24.5 kHz were obtained for Ca(2)RhD(5) and 68.3 and 41.7 kHz for Ca(2)IrD(5) and are assigned to the planar and apical deuterium positions, respectively. Differential scanning calorimetric study of the transition in Ca(2)IrH(5) located a reversible phase transition at 284 K with an enthalpy change of 650 J mol(-1) and entropy change of 2.3 J K(-1) mol(-1).
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".