4-(<i>N</i>,<i>N</i>-Dimethylamino)pyridine-Protected Au Nanoparticles: Versatile Precursors for Water- and Organic-Soluble Gold Nanoparticles
Bibliographic record
Abstract
Ligand-exchange reactions of 4-( N, N -dimethylamino)pyridine-capped gold nanoparticles (DMAP−Au NP) with functionalized thiols (RSH) were investigated. A simple, convenient, and facile synthesis method has been developed. An important feature of this method is its requirement of only very modest quantities of excess thiol ligand. DMAP−Au NP prove to be versatile precursors for both water- and organic-soluble gold NP. DMAP is readily displaced by various functionalized thiols ranging from mercaptocarboxylic acids to ferrocene-terminated thiols. UV−vis spectroscopy and transmission electron microscopy (TEM) confirm that the mean diameter and the size dispersity of the initial DMAP−Au NP were retained upon ligand exchange. The RS−Au NP thus prepared were efficiently purified by gel permeation chromatography (GPC) with neither residual DMAP nor RSH detected in the final product.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".