Studies in the Chemistry of Some New 1,2,4-thiadiazolidine by Oxidative Cyclisation
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Recently in this laboratory a novel series of Hector’s bases (1,2,4-thiadiazolidine) had been synthesized. 1-substituted-3formamidinothiocarbamides (1a-f) and 1,3-Bis(N-substitutedthioamido)guanidines (1g-l) were oxidatively cyclised by using liquid bromine as oxidizing agent in chloroform medium to synthesized yet new series of Hectors bases viz; 3-imino-5-substitutedimino-1,2,4-thiadiazolidine (2a-f) and 3-substitutedthioamidoimino-5-substitutedimino-1,2,4-thiadiazolidine (2g-l) respectively The oxidative cyclisation of (1a-l) was also carried out by making use of H2O2 in concentrated HCl as oxidizing agent. The Hector’s bases isolated in these reactions were characterized on the basis of conventional elemental analysis, chemical characteristics and IR and PMR spectral analysis.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it