Photooxidation Pathway of Sulforhodamine-B. Dependence on the Adsorption Mode on TiO<sub>2</sub> Exposed to Visible Light Radiation
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Bibliographic record
Abstract
The temporal course of the photooxidation of sulforhodamine-B (SRB) in aqueous media illuminated by visible wavelengths in the presence of TiO 2 has been examined to determine the nature of the intermediate species produced and to explore the operative reaction pathway(s). Two pathways are described to account for the differences in the final photooxidation products whose nature depends on the different modes of adsorption of the dye on the metal-oxide mediator. In the SRB/TiO 2 system, when SRB is adsorbed on the positively charged TiO 2 particle surface through a sulfonate group cleavage of the SRB chromophore structure predominates and N -de-ethylation occurs only to a slight extent with the major photooxidation products being diethylamine and carbon dioxide. In the presence of the anionic dodecylbenzenesulfonate surfactant DBS, when SRB is near the negatively charged DBS/TiO 2 interface through the positive diethylamine group N -de-ethylation occurs preferentially before destruction of the structure with the major products being acetaldehyde and carbon dioxide.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it