Novel Bowl-Shaped Morphology of Crew-Cut Aggregates from Amphiphilic Block Copolymers of Styrene and 5-(<i>N</i>,<i>N</i>-Diethylamino)isoprene
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Bibliographic record
Abstract
A new morphology of crew-cut aggregates prepared from highly asymmetric triblock copolymers of 5-( N, N -diethylamino)isoprene and styrene in dilute solution is reported. After quaternization of the polar block, using dimethyl sulfate, the copolymers consist of a long block of polystyrene (PS) with short poly[5-( N, N, N -diethylmethylammonium)isoprene] (PAI) blocks at both chain ends. The aggregates were prepared by first dissolving the copolymers in a common solvent for both blocks and then adding water to induce the segregation of the PS chains. 1,4-Dioxane, THF, or a DMF/THF mixture was used as the common solvent in the preparation of these structures. The bowl-shaped aggregates are essentially highly polydisperse spheres, containing an asymmetrically placed single void space, which has broken through the surface. The continuous phase is composed of an assembly of reverse micelles (PAI core and PS corona) with hydrophilic PAI chains surrounding the structure at the polymer/aqueous solution interface. It is believed that the formation of the bowl-shaped morphology is under kinetic control and does not represent an equilibrium state. A possible mechanism for the formation of this aggregate is proposed, based on two other previously reported crew-cut morphologies from diblock copolymers. This study illustrates the importance of the preparative conditions on the self-assembly of nonequilibrium aggregates from amphiphilic block copolymers.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it