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Record W1981765261 · doi:10.1002/ange.200353051

Partitioning of Solvent Effects and Intrinsic Interactions in Biological Recognition

2004· article· en· W1981765261 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAngewandte Chemie · 2004
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsChemistrySolventStereochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Teile und erkenne: Mithilfe eines neuartigen Ansatzes können Lösungsmitteleffekte und intrinsische Wechselwirkungen bei der Assoziation von Biomolekülen getrennt betrachtet werden (siehe Bild). Um die Enthalpie für die Solvensreorganisation bei der Bildung einer intermolekularen Wasserstoffbrücke in einem solchen Komplex zu bestimmen, werden die Lösungs- und Gasphasenstabilitäten von strukturell verwandten Komplexen verglichen. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2004/z53051_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.275

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.023
GPT teacher head0.241
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it