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Record W1982239037 · doi:10.1063/1.1413966

Spectral density, memory function, and mean relaxation time for resonant subsystem-reservoir interactions

2001· article· en· W1982239037 on OpenAlexafffund
Joshua Wilkie

Bibliographic record

VenueThe Journal of Chemical Physics · 2001
Typearticle
Languageen
FieldPhysics and Astronomy
TopicSpectroscopy and Quantum Chemical Studies
Canadian institutionsSimon Fraser University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsQuantum decoherenceOperator (biology)Master equationRelaxation (psychology)Hermitian matrixBloch equationsStatistical physicsFunction (biology)Density matrixSpectrum (functional analysis)Quantum mechanicsPhysicsChemistryQuantum

Abstract

fetched live from OpenAlex

We show that the projection operators P usually employed to derive the Nakajima–Zwanzig master equation are non-Hermitian. As a consequence the operator QLQ which governs the dynamics of subsystem-reservoir interactions (here Q=1−P and L is the Liouville operator) is also non-Hermitian and possesses a complex temperature-dependent spectrum of resonances. We use the self-consistent Born approximation to derive a formula for the spectral density of QLQ. From this spectral density we calculate the memory function and mean relaxation time of subsystem-reservoir correlations. These formulas are compared with numerical results obtained from the spin–spin-bath model to test their accuracy. The memory function and mean relaxation time are essential ingredients for the SRA (statistical resonance approximation) theory of microscopic dissipation and decoherence. We show that the SRA master equation preserves positivity when the memory function derived in this paper is employed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.266
Threshold uncertainty score0.310

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.257
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations24
Published2001
Admission routes2
Has abstractyes

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